Hi Every body
I found this solution very quick and easy both for anchored categories and non anchored categories in magento for changing the default limit of 3 products in each row of products to any desired numbers

I’m sure you would overcome this so easy so do my instructin without any stress

first go to

/app/design/frontend/default/hellowired/layout

then choose to edit catalog.xml in that directory

for non anchored categories please find somthing similar to this

<catalog_category_default translate="label">
        <label>Catalog Category (Non-Anchor)</label>
        <reference name="left">
            <block type="catalog/navigation" name="catalog.leftnav" after="currency" template="catalog/navigation/left.phtml"/>
        </reference>
        <reference name="content">
            <block type="catalog/category_view" name="category.products" template="catalog/category/view.phtml">
                <block type="catalog/product_list" name="product_list" template="catalog/product/list.phtml">
                    <block type="catalog/product_list_toolbar" name="product_list_toolbar" template="catalog/product/list/toolbar.phtml">
                        <block type="page/html_pager" name="product_list_toolbar_pager"/>
                        <!-- The following code shows how to set your own pager increments -->
                        <!--
                           <action method="setDefaultListPerPage"><limit>4</limit></action>
                           <action method="setDefaultGridPerPage"><limit>9</limit></action>
                           <action method="addPagerLimit"><mode>list</mode><limit>2</limit></action>
                           <action method="addPagerLimit"><mode>list</mode><limit>4</limit></action>
                           <action method="addPagerLimit"><mode>list</mode><limit>6</limit></action>
                           <action method="addPagerLimit"><mode>list</mode><limit>8</limit></action>
                           <action method="addPagerLimit" translate="label"><mode>list</mode><limit>all</limit><label>All</label></action>
                       -->
                    </block>
                    <action method="addColumnCountLayoutDepend"><layout>empty</layout><count>6</count></action>
                    <action method="addColumnCountLayoutDepend"><layout>one_column</layout><count>5</count></action>
                    <action method="addColumnCountLayoutDepend"><layout>two_columns_left</layout><count>4</count></action>
                    <action method="addColumnCountLayoutDepend"><layout>two_columns_right</layout><count>4</count></action>
                    <action method="addColumnCountLayoutDepend"><layout>three_columns</layout><count>3</count></action>
                    <action method="setColumnCount"><columns>4</columns></action>
                    <action method="setToolbarBlockName"><name>product_list_toolbar</name></action>
                </block>
            </block>
        </reference>
    </catalog_category_default>

Please note this line that it is not there by default and has been added manually
4
the number 4 that is nested between tag will define the limit of amount of columns in each row of products items

the same as non anchored categories you jus need to add
4

that will finally look similar to this

    <catalog_category_layered translate="label">
        <label>Catalog Category (Anchor)</label>
        <reference name="left">
            <block type="catalog/layer_view" name="catalog.leftnav" after="currency" template="catalog/layer/view.phtml"/>
        </reference>
        <reference name="content">
            <block type="catalog/category_view" name="category.products" template="catalog/category/view.phtml">
                <block type="catalog/product_list" name="product_list" template="catalog/product/list.phtml">
                    <!-- <action method="addReviewSummaryTemplate"><type>default</type><template>review/helper/su.phtml</template></action> -->
                    <block type="catalog/product_list_toolbar" name="product_list_toolbar" template="catalog/product/list/toolbar.phtml">
                        <block type="page/html_pager" name="product_list_toolbar_pager"/>
                        <!-- The following code shows how to set your own pager increments -->
                        <!--
                            <action method="setDefaultListPerPage"><limit>4</limit></action>
                            <action method="setDefaultGridPerPage"><limit>3</limit></action>
                            <action method="addPagerLimit"><mode>list</mode><limit>2</limit></action>
                            <action method="addPagerLimit"><mode>list</mode><limit>4</limit></action>
                            <action method="addPagerLimit"><mode>list</mode><limit>6</limit></action>
                            <action method="addPagerLimit"><mode>list</mode><limit>8</limit></action>
                            <action method="addPagerLimit" translate="label"><mode>list</mode><limit>all</limit><label>All</label></action>
                            <action method="addPagerLimit"><mode>grid</mode><limit>3</limit></action>
                            <action method="addPagerLimit"><mode>grid</mode><limit>6</limit></action>
                            <action method="addPagerLimit"><mode>grid</mode><limit>9</limit></action>
                            <action method="addPagerLimit" translate="label"><mode>grid</mode><limit>all</limit><label>All</label></action>
                        -->
                    </block>
                    <action method="addColumnCountLayoutDepend"><layout>empty</layout><count>6</count></action>
                    <action method="addColumnCountLayoutDepend"><layout>one_column</layout><count>5</count></action>
                    <action method="addColumnCountLayoutDepend"><layout>two_columns_left</layout><count>4</count></action>
                    <action method="addColumnCountLayoutDepend"><layout>two_columns_right</layout><count>4</count></action>
                    <action method="addColumnCountLayoutDepend"><layout>three_columns</layout><count>3</count></action>
                    <action method="setToolbarBlockName"><name>product_list_toolbar</name></action>
                </block>
            </block>
        </reference>
    </catalog_category_layered>

    <catalog_category_layered_nochildren translate="label">
        <label>Catalog Category (Without Subcategories)</label>
        <remove name="right.reports.product.viewed" />
        <reference name="right">
            <block type="reports/product_viewed" before="right.permanent.callout" name="left.reports.product.viewed" template="reports/product_viewed.phtml" />
        </reference>
    </catalog_category_layered_nochildren>

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